THE A'LEVEL VIEW OF IONIC BONDING Electrons are transferred from one atom to another resulting in the formation of positive and negative ions. The electrostatic attractions between the positive and negative ions hold the compound together. So what's new? At heart - nothing. What needs modifying is the view that there is something magic about noble gas structures. There are far more ions which don't have noble gas structures than there are which do. Some common ions which don't have noble gas structures You may have come across some of the following ions in a basic course like GCSE. They are all perfectly stable , but not one of them has a noble gas structure. Fe 3+ [Ar]3d 5 Cu 2+ [Ar]3d 9 Zn 2+ [Ar]3d 10 Ag + [Kr]4d 10 Pb 2+ [Xe]4f 14 5d 10 6s 2 Noble gases (apart from helium ) have an outer electronic structure ns 2 np 6 .
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Showing posts from April 29, 2014
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Some other examples of ionic bonding magnesium oxide Again, noble gas structures are formed, and the magnesium oxide is held together by very strong attractions between the ions. The ionic bonding is stronger than in sodium chloride because this time you have 2+ ions attracting 2- ions. The greater the charge, the greater the attraction. The formula of magnesium oxide is MgO. calcium chloride This time you need two chlorines to use up the two outer electrons in the calcium. The formula of calcium chloride is therefore CaCl 2 . potassium oxide Again, noble gas structures are formed. It takes two potassiums to supply the electrons the oxygen needs. The formula of potassium oxide is K 2 O.
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Ionic bonding in sodium chloride Sodium (2,8,1) has 1 electron more than a stable noble gas structure (2,8). If it gave away that electron it would become more stable. Chlorine (2,8,7) has 1 electron short of a stable noble gas structure (2,8,8). If it could gain an electron from somewhere it too would become more stable. The answer is obvious . If a sodium atom gives an electron to a chlorine atom, both become more stable. The sodium has lost an electron, so it no longer has equal numbers of electrons and protons. Because it has one more proton than electron, it has a charge of 1+. If electrons are lost from an atom, positive ions are formed . Positive ions are sometimes called cations. The chlorine has gained an electron, so it now has one more electron than proton . It therefore has a charge of 1-. If electrons are gained by an atom, negative ions are formed. A negative ion is sometimes called an anion. The nature of the bond The sodiu...